現(xian)在太(tai)陽(yang)(yang)(yang)(yang)能(neng)路燈(deng)系統中(zhong)鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)的(de)(de)因為(wei)鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)的(de)(de)重量(liang)輕、容(rong)量(liang)大、壽命長、性價比高(gao)等優點使用(yong)越來越廣泛，太(tai)陽(yang)(yang)(yang)(yang)能(neng)路燈(deng)、太(tai)陽(yang)(yang)(yang)(yang)能(neng)草(cao)坪(ping)燈(deng)、太(tai)陽(yang)(yang)(yang)(yang)能(neng)庭(ting)院(yuan)燈(deng)等太(tai)陽(yang)(yang)(yang)(yang)能(neng)發電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)系統中(zhong)使用(yong)鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)也越來越普遍(bian)，就太(tai)陽(yang)(yang)(yang)(yang)能(neng)路燈(deng)、太(tai)陽(yang)(yang)(yang)(yang)能(neng)庭(ting)院(yuan)燈(deng)、太(tai)陽(yang)(yang)(yang)(yang)能(neng)草(cao)坪(ping)燈(deng)中(zhong)的(de)(de)鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)的(de)(de)工(gong)作原(yuan)(yuan)理、鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)的(de)(de)工(gong)作結構(gou)、鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)的(de)(de)優缺點等問題(ti)，筆者根據自己的(de)(de)工(gong)作票實踐及有關理論略作總結，僅供(gong)參考。鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)的(de)(de)工(gong)作原(yuan)(yuan)理鋰(li)(li)(li)(li)金屬(shu)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)一般是使用(yong)二(er)氧(yang)化錳為(wei)正極(ji)(ji)材料(liao)、金屬(shu)鋰(li)(li)(li)(li)或其合(he)(he)(he)金金屬(shu)為(wei)負極(ji)(ji)材料(liao)、使用(yong)非水(shui)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解質溶液的(de)(de)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)，是分別用(yong)二(er)個能(neng)可逆地嵌入與脫嵌鋰(li)(li)(li)(li)離(li)(li)(li)子(zi)的(de)(de)化合(he)(he)(he)物作為(wei)正負極(ji)(ji)構(gou)成的(de)(de)二(er)次電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)。鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)是通過正負極(ji)(ji)的(de)(de)化學反(fan)應產(chan)生電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)子(zi)進行充(chong)放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)的(de)(de)，電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)充(chong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)時，陰極(ji)(ji)中(zhong)鋰(li)(li)(li)(li)原(yuan)(yuan)子(zi)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)離(li)(li)(li)成鋰(li)(li)(li)(li)離(li)(li)(li)子(zi)和電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)子(zi)，并(bing)且鋰(li)(li)(li)(li)離(li)(li)(li)子(zi)向陽(yang)(yang)(yang)(yang)極(ji)(ji)運動與電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)子(zi)合(he)(he)(he)成鋰(li)(li)(li)(li)原(yuan)(yuan)子(zi)。放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)時，鋰(li)(li)(li)(li)原(yuan)(yuan)子(zi)從石墨晶(jing)體內陽(yang)(yang)(yang)(yang)極(ji)(ji)表(biao)面(mian)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)離(li)(li)(li)成鋰(li)(li)(li)(li)離(li)(li)(li)子(zi)和電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)子(zi)，并(bing)在陰極(ji)(ji)處合(he)(he)(he)成鋰(li)(li)(li)(li)原(yuan)(yuan)子(zi)。所以，在該電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)中(zhong)鋰(li)(li)(li)(li)永遠以鋰(li)(li)(li)(li)離(li)(li)(li)子(zi)的(de)(de)形態(tai)出(chu)現(xian)，不(bu)會以金屬(shu)鋰(li)(li)(li)(li)的(de)(de)形態(tai)出(chu)現(xian)，所以這種電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)叫做鋰(li)(li)(li)(li)離(li)(li)(li)子(zi)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)。充(chong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)正極(ji)(ji)上(shang)發生的(de)(de)反(fan)應為(wei)LiCoO2==Li(1-x)CoO2+XLi++Xe-(電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)子(zi))充(chong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)負極(ji)(ji)上(shang)發生的(de)(de)反(fan)應為(wei)6C+XLi++Xe-=LixC6充(chong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)總反(fan)應：LiCoO2+6C=Li(1-x)CoO2+LixC6鋰(li)(li)(li)(li)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)時也是化學反(fan)應，其放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)反(fan)應式：Li+MnO2=LiMnO2

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